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Solar reforming
Why make oxygen from water if you could mitigate waste and
make useful chemicals instead?
Solar fuel synthesis is a sustainable and potentially economical
technology for producing energy carriers such as “green” H2 fuel
through water splitting or liquid fuels from CO2 reduction. Such
classical solar fuel reactions are usually limited by the water
oxidation half-reaction, which is kinetically and energetically
demanding, requires often expensive catalysts and produces solely
O2. Our research aims to overcome these challenges by using
alternative oxidation half-reactions to drive the breakdown of
waste polymers or chemicals into valuable organic products, thus
mitigating waste, generating products of high value and reducing
the thermodynamic and kinetic constraints of the oxidative
half-reaction. We utilise a variety of novel photocatalysts,
including quantum dots and carbon-based light absorbers, as well
as photoelectrochemical platforms to convert plastic- or
biomass-derived waste into organics and fuel using our solar
reforming technology. The oxidative upcycling of biomass and
plastic waste can thereby by coupled to the reductive production
of H2 or fuels from CO2 reduction.
Our aim is to enhance the sustainability and economic value of
solar fuel production by developing processes that simultaneously
produce fuels and drive value-added organic transformations while
mitigating waste.
Selected recent publications
Solar-driven reforming of solid waste for a sustainable future.
Uekert, T.; Pichler, C. M.; Reisner, E. Nat. Sustain.,
2021, 4, 383-391.
Solar reforming as an emerging technology for circular chemical industries.
Bhattacharjee, S.; Linley, S.; Reisner, E. Nat. Rev. Chem., 2024, 8, 87-105.